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Aluminum is one of Astroneer's key progression materials. It is used for vehicles, power items, rails, shuttles, and the Oxygenator, so getting a reliable supply early makes exploration much easier.

Aluminum is made by smelting Laterite in a Smelting Furnace. Laterite is a reddish-brown ore usually found underground, especially in deeper cave layers.
A second option is trading 1x Scrap at the Trading Platform for 1x Laterite.

Bring survival supplies before digging deep for Laterite. Oxygen Filters and Power Cells are useful because cave trips can run long, and suffocating beside the ore you needed is not efficient resource planning.
Craft the Smelting Furnace at the Medium Printer with 2x Resin and 1x Compound.

At least one Aluminum is required for the Smelteringly Hot mission, which also asks players to unlock and print a Smelting Furnace.
Aluminum is used in these recipes:
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